Maysville is an unincorporated village in the U.S. state of Arkansas. It is within Benton County close to Coats School at Spavinaw Creek Rd. and Sellers Farm at Old Hwy. on State Line. They are listed both on the National Register of Historic Places. It has a total land area of 2.33 square miles at 36°24′13″N 94°36′07″W. The elevation is 1,043 feet above sea level. As of the 2010 census data, it had a total population of 426. Estimated per capita income in 2015 was $30,237. It is using Zip code 72747.